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Kinetic and mechanistic investigation of oxidation of 3-methylindole by peroxodisulphate using ethanol medium

Author:

Stephen, J., Nichodemus, M., Subramani, K., Shankaran, K. R., Muniyappan, K.

Subject Area:

Physical Sciences and Engineering

Abstract:

The kinetic studies of oxidation of 3-methylindole (3-MI) by Peroxodisulphate (PDS) has been carried out in ethanol medium. A total second order, first order first order each with respect to [3-MI] and [PDS] has been observed. The reaction was unaffected by increase of [H+]. Increase of percentage of ethanol decreases the rate. Variation of ionic strength had no influence on the rate. Activation and thermodynamic parameters have been calculated from kinetic values. A suitable mechanism scheme based on these observations is proposed.

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