In the present scenario Data Mining is an emerging powerful tool for analyzing the data. Data mining is the process of extracting the valid, relevant and useful information from the data. And association belongs to the discovery data mining techniques, which are used to find patterns inside the data. This paper deals with the some of the measures of association for data mining. And the goal of the quest paper is to use the statistical method of association for mining the data. The method is applied on the census data and it is found that the performance of new method is giving satisfactory results.