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Synthetic and spectral studies on complexes of some transition metals with bis-biacetyl- 2-amminothiophenol

Author: 
Anita Kumari and Yadav, K.
Subject Area: 
Physical Sciences and Engineering
Abstract: 

Binuclear complexes of Co(II), Ni(II), Cu(II) and Zn(II) with bis-biacetyl- 2-aminothiophenol (Schiff base) ligand have been synthesized and characterized on the basis of molar mass, elemental analysis, IR and electronic spectral studies, molar conductance and magnetic susceptibility measurement. On the basis of above physicochemical and spectrometric measurements it is proposed that the compounds act in a bi-dentate manner. Such complexes have varieties of useful pharmaceutical activity and many of them gained wide acceptance in clinical practice. The resulting complexes have been tested for their antifungal activity against various organisms. Complexes, excepting that of Zn(II), are colored. Electronic spectra and magnetic susceptibility study proposes octahedral geometry of the complexes.

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