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Environmentally benign and facile one-pot synthesis of cyanamides mediated by phase transfer reagent ethyltriphenylphosphonium tribromide

Author:

Upasana Bora Sinha, Dipak Sinha and Latonglila Jamir

Subject Area:

Physical Sciences and Engineering

Abstract:

A mild and improved procedure is reported for the synthesis of cyanamides from the corresponding dithiocarbamic acid salts via a desulfurization strategy using phase transfer reagent ethyltriphenylphosphonium tribromide (ETPPTB) and sodium bicarbonate in water / ethyl acetate biphasic medium. This method is highly appealing because of its one-pot process, convenient operation, environmental friendly, mild reaction conditions and broad substrate scope.

PDF file:

Download 4540.pdf

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